The h 1nmr of metal complexes compared with schiff base ligand infers that there is no appreciable change in the signals of the complex as no hydrogen involves in chelation process. Lin lili liu xiaohua feng xiiaoming college of chemistry, sichuan university, chengdu 610064, china. Xray crystallographic analysis of a closely related chromium complex reveals a bridged, dimeric structure bearing aquobound six. Synthesis, crystal structure and antibacterial activity of a group of mononuclear manganeseii schiff base complexes. Synthesis, characterization and antimicrobial activity of. The stabilization of chromiumiv and chromiumv in aqueous systems has now been made through designed alterations in franckcondon barriers for the interconversion of various oxidation states of chromium. New criii complexes with tridentate base schiff nn. Synthesis, characterization and biological activity of. Enantioselective ring opening of meso aziridines catalyzed. These complexes with a cocatalyst are active catalysts in the coupling of co 2 epoxides up to 900 g of polycarbonateg cr was obtained from cyclohexene oxideco 2 a conversion up to 97% in cyclic carbonate was obtained from styrene oxideco 2. Read syntheses of chromiumiii complexes with schiffbase ligands and their catalytic behaviors for ethylene polymerization, journal of molecular catalysis a.
We used spectroscopic techniques including ir, uvvis. Chromium iii schiff base complexes have been synthesized using schiff base formed by the condensing by the. The catalytic activity of the prepared solid catalysts was investigated for the. Schiff bases have been synthesized by condensing nicotinamide with methyl isobutyl ketone mkn and 2hydroxy acetophenone han.
The work described in this thesis mainly covers the investigations of a series of conjugated schiffbase macrocycles and metal salphen complexes. Both the ligands and the complexes synthesized are characterized by c, h, n, cl and metal analyses, ir, uvvis, tga, and magnetic susceptibility for tentative structure. The kinetics of the aqua ligand substitution in the complexes crschiffbasehzo by thiocyanate have been. A number of schiffbase complexes have been used as oxygen carriers to mimic complicated biological systems 7, 11. Coordination complexes with metal ions cuii, niii, coii, feiii, mnii, criii, and voii with six ligands formed by condensation products using azides and aldehydes or ketones are characterized. Complexes based on schiffbase ligands play important roles in biomedical 8, 9, biomimetic, and catalytic systems 10, 11 and in supporting liquid crystalline phases. Eight chromiumiii complexes of tetradentate schiff bases have been prepared in situ by condensing of a substituted salicylaldehyde compound with ethylenediamine. Synthesis and characterization of chromium iii schiff base.
Preparation of artificial metalloenzymes by insertion of. Preparation, characterization and antimicrobial activity. A large number of schiff base n2o2 complexes have been reported so far, and their catalytic and biological properties have been studied intensively 1521. Thermal behavior of tetradentate schiff base chromiumiii. Mniii ion in the highspin state with s 2 3d 4 is described by 5 d ground term. In vitro cytotoxicity activity of novel schiff base ligand. The metal percentages of newly synthesized schiff base metal complexes which are shown in table 3, give a good agreement with the proposed formula calculated, and confirm binding of the metal ion to ligand sites. Coordination complexes of criiiwith four tridentate schiff base ligands viz. Preparation of artificial metalloenzymes by insertion of chromium iii schiff base complexes into apomyoglobin mutants. Asymmetric catalysis of heteroene reactions with tridentate schiff. Characterization of complexes synthesized using schiff. Synthesis and characterization of some chromiumiii complexes of. In an octahedral ligand field, the latter splits onto 5 e g and 5 t 2g levels.
C nmr spectra of schiff base ligand and metal complexes are summarised in table 3 and given in fig. From mic values, it was found that cul and voivl were somewhat more potent among other synthesized schiff base metal complexes. In the present study new schiff base of en4thiophen2 ylmethyleneamino phenylsulfonyl acetamide metal complexes were synthesized and then characterized by various physicochemical and spectral analytical techniques. The salen anion forms complexes with most transition metals. Molecular and biomolecular spectroscopy on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Files available from the acs website may be downloaded for personal use only. These complexes are usually prepared by the reaction of h 2 salen proligand with metal precursors containing builtin bases, such as alkoxides, metal amides, or metal acetate. Tridentate schiff base chromium complexes derived from 1amino2indanol were identified as the optimal catalysts. During the original schiff base complexes crsalprcl 2cl the schiff base also tend to adopt a approximate squareplanar geometry. Asymmetric reactions catalyzed by chiral tridentate schiff. The n1c1c2c3n2cr forms a sixmember ring with the n1crn2 angle 91. The schiff base and its zinc and antimony complexes are strongly active against leukemic cells cd50 2. Thermal behavior of tetradentate schiff base chromiumiii complexes article pdf available in journal of thermal analysis and calorimetry 1152. Preparation of zinc oxide nanomaterial using unsymmetrical.
The reaction of nitric oxide with some of the chromiumiischiff base complexes gave chromiumiii products of indefinite composition, but three 15nnitrosyls of cobaltiischiff base complexes have been isolated. Iii complexes of a homologous series of schiffbase. The complexes were synthesized by template method and characterized by elemental analysis chns. Elemental, spectroscopic and magnetic studies of the reported complexes revealed the proposed structures. Chromiumiii complexes of schiff bases sciencedirect. Ruiii, criii, feiii complexes of schiff base ligands bearing. A catalytic method for the enantioselective ring opening of meso aziridines by tmsn3 is described. Synthesis and characterization of chromiumiii schiff base complexes.
The complexes were used for the selective oxidation of alcohols by 30% hydrogen peroxide without any organic solvent, phase transfer catalyst or additive. Asymmetric reactions catalyzed by chiral tridentate schiff basemetal complexes. Complexes of chromiumii with some betadiketones, 2. Systhesis and characterization of some chromium iii schiff base. Mixedligand copperii complexes with diethylenetriamine and histidine or methioninehydroxamic acids in water solution. This method leads directly to enantioenriched hydroxy silyl enol ether derivatives, which are known to be useful intermediates for the stereocontrolled synthesis of substituted polyol frameworks. Equatorially coordinated macrocyclic and schiff base ligands influence the reorganizational barriers for the conversion of criiicrivcrvcrvi. Synthesis, spectral, thermal and biological studies. Chiral schiff bases according to the general formula. Read structure, photochemistry and magnetic properties of tetrahydrogenated schiff base chromiumiii complexes, spectrochimica acta part a. This study focuses on the synthesis of coii and criii schiff base complexes obtained from thiourea. The proligand may also be treated with a metal halide, with or without an added base lastly, the proligand may. A series of symmetrical tetradentate schiff bases containing the n 2 o 2 donor set and their corresponding chromiumiii complexes have been synthesized and spectrally characterized. Compared with a square planar structure for individual crystalline schiff base complexes, complexes immobilized on a silica surface suffer a tetrahedral distortion due to the anchoring of a ligand foot to the nanoparticle surface, and that can be one of the causes of a raise in their reaction activity.
It has been shown that a very low field 15n nmr signal clearly indicates the presence of a bent mno group. Microwave synthesis and antimicrobial activity of some copper ii, cobalt ii, nickel ii and chromium iii complexes with schiff base 2, 6pyridinedi carboxaldehydethiosemicarbazone. Preparation of zinc oxide nanomaterial using unsymmetrical schiff base complexes maldhure ak 1 and aswar as 2. Pdf schiff base metal complexes of chromiumiii, manganeseiii. Iii complexes of a homologous series of schiffbase ligands. Systhesis and characterization of some chromium iii. The obtained complexes showed promising antimicrobial activity when compared to those of parent ligand. However, because of the further oxidation products, the selectivities cannot be exceeded 5060% fig. Preparation of artificial metalloenzymes by insertion of chromiumiii schiff base complexes into apomyoglobin mutants. Insertion of a symmetric metal complex, cr iii 5,5.
A series of chromiumiii schiff base complexes immobilized on mcm41 were prepared and characterized by various physicochemical and spectroscopic methods. This can be easily described by the following example. Complexes of ironiii and chromium iii salen and salophen schiff bases with bridging 1,3,5. These compounds have been synthesized by conventional as well as microwave methods and characterized by. Bydirect interaction of the schiff base with the metal salts the schiff base can be synthesized without using the metal ion and then followed by addition of the metal ion as salt solution for complex formation. Schif f bases of thiodiazole have good plant growth regulator activity towards auxin and cytokin95. Metal complexes have been prepared by interacting these schiff bases with metal ions viz. Tridentate schiff base chromiumiii complex 1 catalyzes the. Microwave synthesis and antimicrobial activity of some. The magnetic moment values of the complexes exhibited the existence of paramagnetic phenomena for a chromium iii complex and diamagnetic phenomena for the other rest complexes. Conjugated schiffbase macrocycles and their metal complexes. Microwave synthesis, spectral, thermal and antimicrobial.
Thanks to their lewis acidic character, znl complexes show interesting. The preparation, electronic and infrared spectra, and magnetic moments of numerous solid complexes of chromiumiii of the type crsbl2xnh2o l nh 3 or. Criii schiff base complexes obtained from thiourea. Chromium iii schiff base complexes have been synthesized using schiff base formed by the condensing by the respective aldehyde with diamene in ethanol rectified. Preparation and spectroscopic studies of feii, ruii. Complexes of general formulation crschiffbaseh2o2x, where schiffbase 1, 2bissalicylideneaminoethane. The same synthetic procedure gives two series of complexes depending on the amount and rate of addition of potassium carbonate used to deprotonate the schiff base. Chemical on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Jahnteller jt distortion lowers the symmetry up to d 4h tetragonal geometry, which leads to an additional splitting of 5 e g into 5 b 1g and 5 a 1g and of 5 t 2g into 5 e g and 5 b 2g. Abstractthis study describes synthesis, spectroscopic characterization and catalytic activities of feii, ruii, pdii and znii complexes with a novel schiff base ligand l derived from methyl 2amino5,5,7,7tetramethyl4,5,6,7tetrahydrobenzobthiophene3carboxylate and terephthalaldehyde. The thermal properties of the complexes were investigated by thermogravimetric techniques. Tridentate schiff base chromiumiii complex 1 catalyzes the asymmetric heteroene reaction between aryl aldehydes and either 2methoxypropene or 2trimethylsilyloxypropene to provide a series of. Xray crystallographic analysis of a closely related chromium complex reveals a bridged, dimeric. The macrocycles with long alkoxy substituents have the.
Approaches to the aqueous chemistry of chromium iv and. Electrochemical, spectroelectrochemical and structural characterization of iridium and ruthenium porphyrins, schiffbase biquinone complexes, copper triazole complexes and flavins. Synthesis of coii and criii salicylidenic schiff base complexes. These complexes have been characterized by elemental analysis, ir and electronic spectra, magnetic moments, xrd and thermal analysis. Schiff base compounds which contain the azomethine imine group rcn are usually prepared by the condensation of a primary amine with an active carbonyl compound 1 it has been often used as chelating agents ligands in the field of coordination chemistry and schiff base metal complexes were of great interest for many years. Tridentate schiff base chromium iii complex 1 catalyzes the asymmetric heteroene reaction between aryl aldehydes and either 2methoxypropene or 2trimethylsilyloxypropene to provide a series of. All the complexes were characterized on the basis of their micro analytical data, elemental analysis, melting points, ir, uv vis spectra and magnetic moment properties. Synthesis and characterization of a novel schiff base. A concerted ene reaction between silyl enol ethers and simple aldehydes is catalyzed by chiral schiff base cr iii complexes with high stereoselectivity see scheme. Synthesis, characterization, and spectroscopic studies of. A series of novel catalysts were prepared by immobilizing chromiumiii schiff base complexes and acidic ionic liquids onto the surface of mcm41, and characterized by ftir, tg, xrd, sem, tem, nh3tpd, icpoes and n2 sorption studies.
The preparation, electronic and infrared spectra, and magnetic moments of numerous solid complexes of chromiumiii of the type crsbl2xnh2o l nh3 or. Unsymmetrical tetradentate schiff base derived from salicylaldehyde, 2hydroxy3methoxy benzaldehyde and ethylenediamine and its complexes with voiv, criii, mniii, feiii and uo2vi have been prepared. New criii hexacoordinated complexes with tridentate nn. Results and discussion previously we observed that the aerial oxidation of chromium ii salts in presence of dibasic quadriden tate schiff bases of salicylaldehyde or substituted sali cylaldehyde in suitable solvents is a good method for the synthesis of schiff base complexes of chromium iii. Structure, photochemistry and magnetic properties of. Electrochemical behavior, structural, morphological, calf. Metal schiff base complexes have been well known for their easy synthesis, stability and wide application 1214. The coordination behavior of the metal ions towards to the investigated schiff base takes place through cn and oh groups. Construction of nanofibers from supramolecular self. Schiff base and its complexes show that the metals exhibited higher antimicrobial activity than the schiff base on comparison. Eight chromium ii complexes of type, crlh2oxxh2o where l schiff base ligand have been synthesized and characterized on the basis of elemental analysis ir. These compounds selfassemble into supramolecular structures through electrostatic or metalligand interactions, and their morphologies were studied by electron microscopy and atomic force microscopy. Syntheses of chromiumiii complexes with schiffbase.
Solvent extraction of metal chelate complexes has been used as a separation method for a long time. Chromiumiii complexes with a bidentate or unidentate. Chromiumiii, manganeseii and ironiii complexes based on. Solvent extraction of chromium and copper using schiff. Synthesis and characterization of some mixed schiff base complexes of copper and nickel. Complexes of general formulation crschiffbaseh2o2x, where schiffbase1, 2bissalicylideneaminoethane. Abstracta tridentate nno donor hydrazine schiff base, hl, was obtained from condensation of pyridine 2carbaldehyde and 4hydroxy. Preparation and spectroscopic investigation of a schiff. Ru3co12 and rucl3 reacted with the schiff base bis2hydroxyacetophenoneethylenediimine hapenh2 to give ruco2hapenh2 and rucl2hapenh2cl. Manganeseii complexes with schiff bases immobilized on.1001 1388 423 1366 1182 1582 242 380 680 1123 1575 92 1620 739 560 109 1101 851 597 625 424 738 60 1029 1580 6 1017 988 691 607 372 1612 197 34 1372 1554 525 483 315 925 719 1083 597